New PDF release: Organolithiums: Selectivity for Synthesis: 23 (Tetrahedron

By Jonathan Clayden

This quantity, quantity 23 within the "Tetrahedron natural Chemistry" sequence, provides organolithium chemistry from the point of view of a man-made natural chemist, drawing from the artificial literature to give a unified evaluation of ways organolithiums can be utilized to make molecules. the improvement of tools for the regioselective synthesis of organolithiums has changed their photo of indiscriminate excessive reactivity with one in all controllable and sophisticated selectivity. Organolithium chemistry has a significant function within the selective development of C-C bonds in either basic and complicated molecules, and for instance has arguably overtaken fragrant electrophilic substitution because the strongest strategy for regioselective functionalisation of fragrant earrings. the dual topics of reactivity and selectivity run during the booklet, which studies the methods through which organolithiums should be shaped and the ways that they react. themes comprise advances in directed metallation, reductive lithiation and organolithium cyclisation reactions, besides a dialogue of organolithium stereochemistry and the function performed through ligands equivalent to (-)-sparteine.

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Organolithiums: Selectivity for Synthesis: 23 (Tetrahedron Organic Chemistry) by Jonathan Clayden

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